Sensor principle of operation

The INTERSCAN voltammetric sensor (U.S. Patent number 4,017,373) is an electrochemical gas detector operating under diffusion controlled conditions.   The sensor principle of operation is described as follows:

Gas molecules from the sample are adsorbed on an electrocatalytic sensing electrode, after passing through a diffusion medium, and are electrochemically reacted at an appropriate sensing electrode potential. This reaction generates an electric current directly proportional to the gas concentration. This current is converted to a voltage for meter or recorder readout.

The diffusion limited current, ilim, is directly proportional to the gas concentration according to the simplified equation…

ilim = nFADC

where ilim is the diffusion limited current in amps,    F is the Faraday constant (96,500 coulombs),    A is the reaction interfacial area in cm2,    n is the number of electrons per mole reactant,    δ is the diffusion path length,    C is the gas concentration in moles/cm3,    and D is the gas diffusion constant, representing the product of the permeability and solubility coefficients of the gas in the diffusion medium.

An external voltage bias maintains a constant potential on the sensing electrode, relative to a nonpolarizable reference counterelectrode in the two-electrode Interscan sensor. Nonpolarizable means that the counterelectrode can sustain a current flow without suffering a change in potential. Thus, the counterelectrode acts also as a reference electrode, eliminating the need for a third electrode and a feedback circuit, as would be required for sensors using a polarizable air counterelectrode.

Interscan sensors—and gas analyzers—are available for

carbon monoxide
chlorine dioxide
ethylene oxide
hydrogen bromide
hydrogen chloride
hydrogen cyanide
hydrogen peroxide
hydrogen sulfide
nitric oxide
nitrogen dioxide
 peracetic acid
propylene oxide
sulfur dioxide

For more information on our analyzers, visit the Products section of this website